- 30 August
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Line
- Roman Safiullin-Carlos Alcaraz Garfia
- Stefanos Tsitsipas-Arthur Fils
- Francisco Comesana-Flavio Cobolli
- Valentin Vacherot-Aleksandar Kovacevic
- Mariano Navone-Novak Djokovic
- Brandon Nakashima-Sebastian Baez
- Alexander Zverev-Lorenzo Sonego
- Marcos Giron-Ignacio Buse
- Matteo Berrettini-Stanislas Wawrinka
- Thiago Agustin Tirante-Adrian Mannarino
- Marin Cilic-Andrey Rublev
- Arthur Fery-Lorenzo Musetti
- Felix Auger Aliassime-Rinky Hijikata
- Alexander Bublik-Jeffrey John Wolf
- Kamil Majchrzak-Hamad Medjedovic
- Zachary Svajda-Daniel Altmaier
- Sho Shimabukuro-Arthur Rinderknech
- Martin Damm-Frances Tiafoe
- Roman Andres Burruchaga-Karen Khachanov
- Jaime Faria-Jenson Brooksby
- Dane Sweeny-Corentin Moutet
- Quentin Halys-Facundo Diaz Acosta
- Daniel Merida Aguilar-Marton Fucsovics
- Sebastian Gorzny-Raphael Collignon
- Filip Misolic-Francisco Cerundolo
- Miomir Kecmanovic-Denis Shapovalov
- Damir Dzumhur-Hubert Hurkacz
- Fabian Marozsan-Michael Zheng
- Jan Choinski-Botic Van De Zandschulp
- Tomas Martin Etcheverry-Vit Kopriva
- Alex Molcan-Benjamin Bonzi
- Luca Van Assche-Cameron Norrie
- Matteo Arnaldi-James Duckworth
- Rafael Jodar-Thanasi Kokkinakis
- Jaume Antoni Munar Clar-Terence Atmane
- Taylor Harry Fritz-Darwin Blanch
- Yannick Hanfmann-Alejandro Tabilo
- Jiri Lehecka-Pablo Carreno Busta
- Yibing Wu-Adam Walton